Friday, June 26, 2009

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In mineralogy, diamond (from the ancient Greek adámas, meaning "proper" or "unalterable") is an allotrope of carbon, where the carbon atoms are arranged in a variation of the face centered cubic crystal structure called a diamond lattice. Diamond is the second most stable form of carbon, after graphite; however, the conversion rate from diamond to graphite is negligible at ambient conditions. Diamond is specifically renowned as a material with superlative physical qualities, most of which originate from the strong covalent bonding between its atoms. In particular, diamond has the highest hardness and thermal conductivity of any bulk material synthesized so far. Those properties determine the major industrial application of diamond in cutting and polishing tools.

Diamond has remarkable optical characteristics. Because of its extremely rigid lattice, it can be contaminated by only few types of impurities, such as boron and nitrogen. Combined with the wide transparency (corresponding to the wide band gap of 5.5 eV), this results in clear, colorless appearance of most natural diamonds. Small amounts of defects or impurities (about one part per million) color diamond blue (boron), yellow (nitrogen), brown (lattice defects), green, purple, pink, orange or red. Diamond also has relatively high optical dispersion, that is ability to disperse light of different colors, which results in its characteristic luster. Excellent optical and mechanical properties, combined with efficient marketing, make diamond the most popular gemstone.

Most natural diamonds are formed at high-pressure high-temperature conditions existing at depths of 140 km to 190 km in the Earth mantle. Carbon-containing minerals provide the carbon source, and the growth occurs over periods from 1 billion to 3.3 billion years, which respectively corresponds to roughly 25% and 75% of the age of the Earth. Diamonds are brought close to the Earth surface through deep volcanic eruptions by a magma, which cools into igneous rocks known as kimberlites and lamproites. Diamonds can also be produced synthetically in a high-pressure high-temperature process which approximately simulates the conditions in the Earth mantle. An alternative, and completely different growth technique is chemical vapor deposition. Several non-diamond materials, which include cubic zirconia and silicon carbide and are often called diamond simulants, resemble diamond in appearance and many properties. Special gemological techniques have been specially developed to distinguish natural and synthetic diamonds and diamond simulants.